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Because this new element (decay product) remains on or within the object, scientists can easily determine how old the object is. A mass spectrometer is a fundamental device in any radiometric dating experiment.
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The Law of Superposition doesn’t tell scientists how old a rock layer is, it only tells them that one layer is older than another.
An Alpha Decay changes the atom because during the decay the atom loses 2 protons.
Relative age dating also means paying attention to crosscutting relationships.